龙马溪页岩弹性各向异性与矿物分布之间的关系探讨   总被引：1，自引：0，他引：1       下载免费PDF全文

伍宇明  兰恒星  黄为清 《地球物理学报》2020,63(5):1856-1866

岩石弹性各向异性特征是普遍存在的,但导致岩石弹性各向异性的原因复杂且仍然存在一定争议.本研究以龙马溪页岩为例,试图建立页岩弹性各向异性和矿物分布之间关系.研究使用无损超声波探测获取岩石弹性各向异性参数,并使用背散射技术获取岩石矿物分布特征.研究通过引进变异系数来描述矿物或孔裂隙在不同方向的差异性,并通过2个正交方向的变异系数建立微观异质性指标,用于表征微观尺度上矿物或孔裂隙在不同方向的差异程度.微观背散射图像显示,龙马溪组页岩主要由石英和伊利石构成,且这两种矿物和孔裂隙在X和Y面上都有定向排列特征.相应地,它们的变异系数在X面和Y面上均表现出随角度增大而降低的特征;而在Z面,石英、伊利石和孔裂隙变异系数变化不明显,这与Z面上矿物和孔裂隙无明显方向性的特点一致.无损超声波探测结果显示,波速在X和Y面上随角度增加而减小,这与主要矿物和孔裂隙变异系数变化趋势相同;而在Z面,波速变化不大,与主要矿物和孔裂隙变异系数变化不明显的特征一致.以上观测结果说明,宏观波速与矿物的微观变异系数明显相关,暗示岩石弹性各向异性与矿物分布直接相关.  相似文献   

LA-ICP-MS in situ analyses of the pyrites in Dongyang gold deposit,Southeast China: Implications to the gold mineralization     

《China Geology》2020,3(2):230-246

The Dongyang gold deposit is a newly discovered epithermal deposit in Fujian Province, Southeast China, along the Circum-Pacific metallogenic belt. Herewith, the authors present mineralogical, scanning electron microscope, and laser ablation inductively coupled clasma mass spectrometry analysis to reveal the relations between Au and Te, As, S, Fe, etc., and discuss the gold precipitation process. The pyrites in this deposit are Fe-deficient, and are enriched in Te and As. The authors infer that As was mainly in form of As-complexes, and Te-Au-Ag inclusions/solid solution also exsits in the Py I. Along with the depletion of Te and As, they were less active chemically in the Py II, and Au may be incorporated into As-rich and Fe-deficient surface sites by chemisorption onto As-rich growth surfaces. Because of the incorporation of new fluid, Te and As became the most active chemically in the Py III, which was the main elements precipitation stage, and As dominantly substituted for S in the lattice of pyrite, due to the more reducing condition. The authors propose Au was in form of invisible gold, and the incorporation of gold can be considered as post-pyrite event, while the Au-bearing minerals were result of post incorporation of gold in arsenian pyrite.  相似文献   

基于沉积过程的数字岩石建模方法研究          下载免费PDF全文

田志  肖立志  廖广志  董虎  田守嶒  宋先知 《地球物理学报》2019,62(1):248-259

本文提出模拟地层沉积及成岩过程的矿物沉积算法,建立数字岩石模型,并通过对比Micro-CT扫描图像和数值模型的局部孔隙度及平均渗流概率函数分布特征,评价建模的准确性.结果表明,由二维扫描提取的粒径信息作为输入参数,模拟矿物沉积过程建模得到的三维数字岩石模型,能够准确重构原始岩心的非均质性及渗流特性,成功应用于泥质砂岩、碳酸盐岩、页岩等存在多矿物或多尺度孔隙的数字岩石建模中.数字岩石物理是正在兴起的重要技术.数字岩石采用超高分辨率先进成像装备,采集和表征微纳尺度岩石结构,在岩石弹性、电性、核磁、渗流特性等数值计算中发挥重要作用.但是,由于三维直接成像在有限视域内难以表征足够的岩石非均质性,提取二维结构统计特征,利用统计或地质过程法重构具有代表性的三维岩石结构成为十分有价值的研究课题,而且,对业界大量存在的岩石薄片及电镜高清二维图像的深度开发应用也具有重要的现实意义.本文发展的新方法,复原沉积过程,较好地解决了孔隙尺度岩石物理定量研究中数值建模与理论计算的技术瓶颈.  相似文献   

Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China     

《Chemie der Erde / Geochemistry》2021,81(2):125748

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   

柴达木盆地一里坪盐湖成盐卤水成分变化及其意义——来自LA- ICP- MS分析石盐流体包裹体组成的证据   总被引：1，自引：0，他引：1  

胡宇飞  汪明泉  赵艳军  焦鹏程 《地质学报》2021,95(7):2109-2120

一里坪盐湖是柴达木盆地一个以富锂卤水为主的干盐湖,蕴藏有丰富的卤水钾锂资源,目前对成矿过程中卤水的成分及其演变规律方面的研究较少.论文选取一里坪盐湖中部钻孔HC2105岩芯的石盐为主要对象,利用激光剥蚀-电感耦合等离子质谱法开展了单个石盐原生流体包裹体成分分析,探讨恢复了一里坪盐湖地区晚更新世以来成盐期的古卤水成分.结果表明,一里坪盐湖下层石盐古卤水Li、B、K等离子浓度均高于上层石盐,这说明晚更新世成矿条件更好.古卤水中Li、B、K和Mg等离子具有正相关性,再结合对Ca离子浓度变化的研究,说明一里坪盐湖的主要物质来源为那棱郭勒河,深部卤水对其物质来源贡献较小;石盐流体包裹体中各离子浓度的演变规律与钻孔沉积韵律以及古气候变化三者基本可以拟合,从而证实盐湖卤水成分变化受到古气候变化的影响,干冷期可能更有利于富锂卤水矿的形成.  相似文献   

Hydrothermal alteration processes in the giant Dahutang tungsten deposit,South China: Implications from litho-geochemistry and mass balance calculation     

《China Geology》2021,4(2):230-244

The giant Dahutang tungsten (W) deposit has a total reserve of more than 1.31 Mt WO₃. Veinlet-disseminated scheelite and vein type wolframite mineralization are developed in this deposit, which are related to Late Mesozoic biotite granite. Four major types of alterations, which include albitization, potassic-alteration, and greisenization, and overprinted silicification developed in contact zone. The mass balance calculate of the four alteration types were used to further understanding of the mineralization process. The fresh porphyritic biotite granite has high Nb, Ta, and W, but low Ca and Sr while the Jiuling granodiorite has high Ca and Sr, but low Nb, Ta, and W concentrations. The altered porphyritic biotite granite indicated that the Nb, Ta, and W were leached out from the fresh porphyritic biotite granite, especially by sodic alteration. The low Ca and Sr contents of the altered Neoproterozoic Jiuling granodiorite indicate that Ca and Sr had been leached out from the fresh granodiorite by the fluid from Mesozoic porphyritic biotite granites. The metal W of the Dahutang deposit was mainly derived from the fluid exsolution from the melt and alteration of W-bearing granites. This study of alteration presents a new hydrothermal circulation model to understand tungsten mineralization in the Dahutang deposit.  相似文献   

Geology and mineralization of the Sanshandao supergiant gold deposit (1200 t) in the Jiaodong Peninsula,China: A review     

《China Geology》2021,4(4):686-719

The Jiaodong Peninsula in Shandong Province, China is the world’s third-largest gold metallogenic area, with cumulative proven gold resources exceeding 5000 t. Over the past few years, breakthroughs have been made in deep prospecting at a depth of 500–2000 m, particularly in the Sanshandao area where a huge deep gold orebody was identified. Based on previous studies and the latest prospecting progress achieved by the project team of this study, the following results are summarized. (1) 3D geological modeling results based on deep drilling core data reveal that the Sanshandao gold orefield, which was previously considered to consist of several independent deposits, is a supergiant deposit with gold resources of more than 1200 t (including 470 t under the sea area). The length of the major orebody is nearly 8 km, with a greatest depth of 2312 m below sea level and a maximum length of more than 3 km along their dip direction. (2) Thick gold orebodies in the Sanshandao gold deposit mainly occur in the specific sections of the ore-controlling fault where the fault plane changes from steeply to gently inclined, forming a stepped metallogenic model from shallow to deep level. The reason for this strong structural control on mineralization forms is that when ore-forming fluids migrated along faults, the pressure of fluids greatly fluctuated in fault sections where the fault dip angle changed. Since the solubility of gold in the ore-forming fluid is sensitive to fluid pressure, these sections along the fault plane serve as the target areas for deep prospecting. (3) Thermal uplifting-extensional structures provide thermodynamic conditions, migration pathways, and deposition spaces for gold mineralization. Meanwhile, the changes in mantle properties induced the transformation of the geochemical properties of the lower crust and magmatic rocks. This further led to the reactivation of ore-forming elements, which provided rich materials for gold mineralization. (4) It can be concluded from previous research results that the gold mineralization in the Jiaodong gold deposits occurred at about 120 Ma, which was superimposed by nonferrous metals mineralization at 118–111 Ma. The fluids were dominated by primary mantle water or magmatic water. Metamorphic water occurred in the early stage of the gold mineralization, while the fluid composition was dominated by meteoric water in the late stage. The S, Pb, and Sr isotopic compositions of the ores are similar to those of ore-hosting rocks, indicating that the ore-forming materials mainly derive from crustal materials, with the minor addition of mantle-derived materials. The gold deposits in the Jiaodong Peninsula were formed in an extensional tectonic environment during the transformation of the physical and chemical properties of the lithospheric mantle, which is different from typical orogenic gold deposits. Thus, it is proposed that they are named “Jiaodong-type” gold deposits.©2021 China Geology Editorial Office.  相似文献   

激光拉曼光谱法在单个流体包裹体研究中的应用进展   总被引：2，自引：2，他引：0  

何佳乐  潘忠习  冉敬 《岩矿测试》2015,34(4):383-391

激光拉曼光谱法以其非破坏性、高灵敏度和高分辨率等特性,一直以来都是研究流体包裹体的重要方法之一。近年来,围绕激光拉曼光谱在流体包裹体中的应用而展开的研究主要集中在半定量-定量测试方面,即在准确定性的基础上,采用高斯-洛仑兹去卷积分峰、低温原位等定量方法获取流体包裹体的成分和含量,从而克服了激光拉曼光谱法应用于溶液中阳离子的定量分析的灵敏度、准确度较低的问题,不仅能获得流体包裹体中一些常温下不具拉曼活性的盐类物质拉曼特征峰信息,还能根据特征峰与浓度、内压之间的线性关系,进一步对盐度和压力等性质进行测定,从而拓展了激光拉曼光谱法在流体包裹体中的应用范围。本文对激光拉曼光谱法应用于分析流体包裹体成分、盐度、同位素和压力所取得的最新进展进行了评述,并认为随着分析测试技术的不断进步,激光拉曼光谱法未来的分析方向也将继续围绕多元复杂体系及其定量方面的研究展开。  相似文献   

安徽铜陵胡村南铜钼矿床流体成矿过程   总被引：1，自引：0，他引：1  

郑泽军  杜杨松  鲁颖淮  陈林杰  杨赫鸣  张芸  任春雷  江勇卫 《矿床地质》2015,34(4):692-710

胡村南铜钼矿床是在安徽铜陵铜(金)矿集区中发现的第一个矽卡岩-斑岩复合型铜钼矿床,在长江中下游成矿带具有特殊性和典型性。文章对该矿床进行了矿床地质和流体包裹体研究,旨在查明该矿床的流体成矿过程。胡村南铜钼矿床流体成矿过程可以划分为高温气成热液期、中高温热液期和低温热液期3个成矿期。高温气成热液期发育钾长石化和矽卡岩化,中高温热液期发育绿泥石化、绿帘石化和绢云母化,而低温热液期主要发育碳酸盐化。其中,中高温热液期为主要矿化期,形成辉钼矿和黄铜矿等多种硫化物网脉。高温气成热液期矿物中发育富液相和含子晶多相包裹体,中高温热液期矿物中也主要发育富液相包裹体和含子晶多相包裹体,但可见少量的富气相包裹体,低温热液期矿物中只发育富液相包裹体。从高温气成热液期经中高温热液期到低温热液期,成矿流体均一温度从435℃以上,经203~458℃,降低到156~276℃;盐度w(NaCleq)从14.0%~64.9%,经4.6%~47.5%,降低到1.0%~15.5%。成矿流体在其演化过程中发生过不混溶作用和沸腾作用。不混溶作用发生在气成热液期,使成矿流体中的成矿元素大量富集。沸腾作用发生在中高温热液期,导致成矿流体中的成矿元素卸载而沉淀出大量金属硫化物。  相似文献   

新疆阿尔泰巴特巴克布拉克铁矿床成矿作用研究   总被引：2，自引：0，他引：2       下载免费PDF全文

杨俊杰  柴凤梅  杨富全  张志欣 《地质科学》2015,(3):879-897

巴特巴克布拉克铁矿床赋存于上志留-下泥盆统康布铁堡组变质火山-沉积岩系中, 近矿围岩为石榴子石矽卡岩、角闪斜长变粒岩和浅粒岩。矿体总体顺层分布, 呈似层状、透镜状及不规则状, 空间上与矽卡岩密切相关。流体包裹体研究表明, 矽卡岩阶段形成的石榴子石中发育纯气体包裹体、气体包裹体、液体包裹体、含子矿物包裹体及熔融包裹体; 退化蚀变阶段发育液体包裹体和少量气体包裹体; 石英-硫化物阶段主要发育液体包裹体、含液体CO₂的三相包裹体及少量纯气体包裹体、气体包裹体和含子矿物包裹体。矽卡岩阶段均一温度变化为217 ℃~499 ℃, 在255 ℃出现峰值, 盐度(NaCl_eq)变化为8.68%~22.65%; 退化蚀变阶段均一温度变化为181 ℃~432 ℃, 在225 ℃出现峰值, 盐度变化为12.85%~22.65%; 石英-硫化物阶段均一温度变化为140 ℃~482 ℃, 在155 ℃出现峰值, 盐度变化为0.18%~42.40%。石榴子石、石英和方解石的 δ¹⁸ O_SMOW 变化为1.8‰~7.1‰, δ¹⁸Ο_Η2Ο为 -4.79‰~4.57‰, δD_SMOW 为 -128‰~-84‰, 表明矽卡岩阶段成矿流体主要为岩浆水, 混合少量大气降水; 石英-硫化物阶段大气降水所占比例明显增加。方解石δ¹³ C_V-PDB 变化为 -3.2‰~-2.0‰, 表明流体中的碳来自深部或地幔。  相似文献